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热浸镀用锌及锌铝合金的恒电流电化学性能
李鑫1,2, 杜鸿雁3, 张杰4,5, 张胜涛3, 魏绪钧1, 李焰4
1.东北大学材料与冶金学院;2.北京矿冶研究总院;3.重庆大学化学化工学院;4.中国科学院海洋研究所;5.中国科学院研究生院
摘要:
在海水腐蚀过程中,热浸镀层金属(或合金)对钢铁基体的阴极保护作用是很重要的因素,只有驱动电位大且稳定、电流效率高、表面腐蚀均匀的镀层才能保证钢材在海水中使用长久。作者按照国标GB/T17848-1999的要求对几种典型的热浸镀用锌及锌铝合金测试了开路电位、工作电位,计算了电流效率,观察了腐蚀产物脱落情况及腐蚀均匀性,评价了各种典型镀层金属(合金)的电化学保护性能。研究表明,Zn的电化学性能最好,Zn-55Al-1.6Si合金的电化学性能最差,Zn-5Al-0.2RE、Zn-5Al-0.1Mg、Zn-6Al-3Mg、Zn-11Al-3Mg-0.2Si、Zn-25Al-0.2Mg-0.2Si和Zn-25Al-0.2RE-0.2Si合金介于二者之间。
关键词:  热浸镀  阴极保护  电流效率  电化学性能
DOI:
分类号:
基金项目:国家自然科学基金资助项目(40306013)
Electrochemical protection performance of hot-dipping Zn and Zn-Al alloys
Abstract:
During corrosion process of hot-dip coatings immersed in seawater, cathodic protection by hot dipping zinc and zine-aluminum alloy coatings to substrate steel is a very important factor. Only the coatings with high and stable driving voltage, high current efficiency and uniform surface corrosion can last long. The electrochemical protection performance of Zn and Zn-Al alloys for hot dip galvanization was examed according to GB/T 17848-1999. The results indicate that Zn showed the best electrochemical performance, Zn-55Al-1.6Si were the worst with many others in between.
Key words:  hot-dip by galvanization  cathodic protection  electrochemical performance  current efficiency
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