| 摘要: |
| 以渤海某原油作为研究对象进行综合模拟风化实验, 探讨了原油中五类PAHs组分的风化规律并筛选出其中稳定的诊断比值。结果表明: 经过50d风化, 原油中PAHs的分布已经发生了较大的改变, 其中萘系类损失最为严重, 菲系列所占的比例有所提高, 二苯并噻吩、屈、芴系列则保持相对稳定, 这为进一步筛选用于溢油来源鉴别的新诊断比值参数提供了一定依据; 经风化检验, 现有常用6种PAHs诊断比值在风化50d后较稳定, 可用于风化溢油的鉴别; 所选取新诊断比值中, 菲和屈系列、烷基取代二苯并噻吩类、烷基取代芴类抗风化能力较强, 共筛选出34种诊断比值可作为溢油鉴别的有效指标。 |
| 关键词: 原油 多环芳烃 风化 诊断比值 |
| DOI：10.11693/hyhz201305008008 |
| 分类号: |
| 基金项目:海洋公益性行业科研专项经费项目, 201205012-4号; 中央级公益性科研院所基本科研业务费专项资金, 2013G11号; 大连理工大学海岸和近海工程国家重点实验室开放基金项目, LP1012号。 |
附件 |
|
| CHANGES OF POLYCYCLIC AROMATIC HYDROCARBONS (PAHS) BASED ON DIAGNOSTIC RATIOS IN CRUDE OIL FROM BOHAI SEA UNDER COMPREHENSIVE WEATHERING CONDITION |
|
CAO Lei1,2,3, HAN Bin, ZHENG Li1,4, YANG Dong-Fang5, WANG Xiao-Ru1,4
|
|
1.First Institute of Oceanography, State Oceanic Administration;2.State Key laboratory of Coastal and offshore engineering, Dalian University of Technology;3.College of Fisheries and Life Science, Shanghai Ocean University;4.State Key laboratory of Coastal and offshore engineering, Dalian University of Technology;5.College of Fisheries and Life Science, Shanghai Ocean University
|
| Abstract: |
| Life Science, Shanghai Ocean University, Shanghai 201306, China)
Abstract We simulated the changes of the polycyclic aromatic hydrocarbons (PAHs) in crude oil from Bohai Sea under comprehensive weathering condition to understand the process of pollution due to oil spill and leak. Some diagnostic ratios were selected. The results show that the distribution patterns of PAHs in crude oil changed greatly after 50 days of weathering. Compounds of naphthalene series disappeared largely, of which phenanthrene (PHE) series increased to some extent, and series of dibenzothiophene, chrysene, and fluorene remained relatively unstable. The six customary diagnostic ratios that applied show strong weathering-resistance. These ratios have been used to identify the oil source. Among 34 diagnostic ratios that selected as effective indicators, the series of phenanthrene, chrysene, alkyl dibenzothiophene, and alkyl fluorene were in strong weathering resistance, being the most indicative to oil spill identification. |
| Key words: crude oil polycyclic aromatic hydrocarbons (PAHs) weathering diagnostic ratio |
